Table 1.
Removal of BF2 from F-BODIPYs using Brønsted acids.
F-BODIPY | dipyrrin | yield (%) | |
TFA | HCl | ||
3 | 14 | 99 | 96 |
4 | 15 | 96 | 98 |
8 | 16 | 100 | 92a |
9 | 17 | 99 | 99 |
11 | 18 | 53b | 53b |
aExtended reaction time (48 hours) was required. bAnalytically pure material was obtained by HPLC purification.