Table 2.
Element | Extraction in H 2 O | Extraction in 0.1 mol L −1 HCl | Extraction in DTPA–CaCl 2 –TEA | Total contents | |||
---|---|---|---|---|---|---|---|
Copper mine environ (site 1) | Former iron mine environ (site 2) | Reference area (site 3) | Urban area (site 4) | ||||
Ag | <0.01 | 0.02 ± 0.01 | <0.01 | 0.47 | 0.76 | 0.46 | 1.09 |
Al | 23.9 ± 16.5 | 62.9 ± 46.2 | 0.78 ± 0.88 | 58992 | 61061 | 59467 | 59643 |
As | <0.25 | <0.25 | <0.25 | 26.9 | 23.4 | 18.9 | 48.7 |
Ba | 0.18 ± 0.05 | 10.9 ± 5.81 | 0.71 ± 0.40 | 311 | 403 | 343 | 437 |
Ca | 104 ± 47.7 | 3421 ± 430 | 1222 ± 197 | 22677 | 20447 | 21954 | 35394 |
Cd | 0.01 ± 0.001 | 0.05 ± 0.03 | 0.05 ± 0.03 | 1.06 | 0.96 | 0.86 | 0.59 |
Cr | 0.04 ± 0.02 | 0.06 ± 0.03 | 0.01 ± 0.003 | 63.6 | 41.9 | 55.8 | 54.2 |
Cu | 0.30 ± 0.06 | 1.57 ± 1.97 | 8.60 ± 6.65 | 100 | 63.7 | 34.3 | 79.0 |
Fe | 27.9 ± 18.1 | 4.43 ± 4.84 | 28.0 ± 33.4 | 43025 | 32629 | 32646 | 31242 |
K | 56.2 ± 15.6 | 155 ± 47.2 | 81.6 ± 26.6 | 23716 | 19805 | 16173 | 20290 |
Li | 0.01 ± 0.004 | 0.04 ± 0.006 | 0.006 ± 0.005 | 7.79 | 5.70 | 7.74 | 9.81 |
Mg | 21.7 ± 6.15 | 305 ± 79.6 | 103 ± 28.7 | 10676 | 6583 | 8956 | 8629 |
Mn | 0.47 ± 0.31 | 44.4 ± 28.5 | 10.6 ± 2.82 | 521 | 577 | 575 | 567 |
Mo | 0.04 ± 0.04 | 0.04 ± 0.02 | 0.03 ± 0.03 | 4.0 | 3.2 | 2.8 | 2.5 |
Na | 6.91 ± 4.67 | 9.73 ± 5.94 | 6.06 ± 5.35 | 8582 | 9248 | 8506 | 7956 |
Ni | 0.18 ± 0.05 | 0.84 ± 0.54 | 0.55 ± 0.22 | 19.6 | 39.0 | 23.9 | 34.0 |
P | 16.6 ± 3.75 | 177 ± 24.8 | 5.19 ± 1.41 | 1385 | 931 | 995 | 2184 |
Pb | 0.25 ± 0.07 | 0.38 ± 0.26 | 1.71 ± 1.15 | 24.4 | 44.8 | 36.8 | 83.9 |
V | 0.08 ± 0.03 | 0.10 ± 0.08 | 0.06 ± 0.04 | 93.8 | 72.2 | 82.7 | 67.9 |
Zn | 0.28 ± 0.11 | 6.02 ± 5.34 | 5.02 ± 5.10 | 78.8 | 72.9 | 73.2 | 181 |
Bold values indicated the maximum extracted content of current element under specific extraction reagents.