Table 1.
Ambient Concentrations | Emission Factors (g kg−1 or # kg−1) | ||||||
---|---|---|---|---|---|---|---|
Formula | Background | Plume-impacted | Units | Mean | Std. Deviation | Median | |
Carbon dioxidea | CO2 | 378.9 | 383.1 | (ppm) | - | - | - |
Sulfur dioxidea | SO2 | 1.69 | 3.75 | (ppb) | 7.1 | 8.31 | 2.91 |
PM2.5a | - | 9.81 | 15.1 | (μg m−3) | 5.35 | 5.39 | 3.05 |
Elemental carbon | - | 0.22b | 0.84c | (μg m−3) | 2.41 | 2.43 | 1.37 |
Particle numbera | - | 9800 | 39400 | (# cm−3) | 3.49E+16 | 3.41E+16 | 2.05E+16 |
Polycyclic aromatic hydrocarbonsd | (mg kg−1) | (mg kg−1) | (mg kg−1) | ||||
9-Methylanthracene | C15H12 | BDLe | 0.07c | (ng m−3) | 0.35 | 0.19 | 0.24 |
Fluoranthene | C16H10 | 0.06 | 0.60 | (ng m−3) | 0.67 | 0.80 | 0.31 |
Acephenanthrylene | C16H10 | BDL | 0.31 | (ng m−3) | 0.49 | 0.43 | 0.31 |
Pyrene | C16H10 | 0.02 | 0.64 | (ng m−3) | 0.70 | 0.34 | 0.52 |
Benzo[ghi]fluoranthene | C18H10 | BDL | 0.64 | (ng m−3) | 1.6 | 0.5 | 1.4 |
Cyclopenta[cd]pyrene | C18H10 | 0.08 | 0.39 | (ng m−3) | 0.65 | 0.34 | 0.54 |
Benz[a]anthracene | C18H12 | 0.02 | 1.45 | (ng m−3) | 1.8 | 2.2 | 0.88 |
Chrysene | C18H12 | 0.07 | 5.44 | (ng m−3) | 8.3 | 8.0 | 4.4 |
Retene | C18H18 | BDL | 0.61 | (ng m−3) | 0.90 | 0.96 | 0.45 |
1-Methylchrysene | C19H14 | BDL | 0.69 | (ng m−3) | 1.2 | 0.9 | 0.9 |
Benzo[b+k]fluoranthene | C20H12 | 0.16 | 9.82 | (ng m−3) | 17 | 13 | 11 |
Benzo[j]fluoranthene | C20H12 | BDL | 0.94 | (ng m−3) | 1.1 | 1.4 | 0.48 |
Benzo[e]pyrene | C20H12 | 0.18 | 5.70 | (ng m−3) | 9.8 | 7.6 | 6.7 |
Benzo[a]pyrene | C20H12 | 0.02 | 1.56 | (ng m−3) | 2.3 | 2.2 | 1.5 |
Perylene | C20H12 | 0.02 | 0.21 | (ng m−3) | 0.35 | 0.26 | 0.25 |
Indeno[1,2,3-cd]pyrene | C22H12 | 0.05 | 1.65 | (ng m−3) | 2.9 | 2.1 | 1.8 |
Benzo[ghi]perylene | C22H12 | 0.06 | 1.66 | (ng m−3) | 3.4 | 2.1 | 2.6 |
Dibenz[ah]anthracene | C22H14 | BDL | 0.53 | (ng m−3) | 1.1 | 0.65 | 0.77 |
Picene | C22H14 | BDL | 0.58 | (ng m−3) | 1.6 | 0.68 | 1.2 |
Sum of quantified PAH | - | - | 33.4 | (ng m−3) | 56 | 44 | 37 |
Determined from samples collected 30 May to 3 June, 2012 (n = 10)
May-June 2011 background (n=28)
greatest plume-impact on June 2, 2012 (n=1)
EF determined from samples collected 28 May to 5 June, 2012 (n = 5)
pre-tire fire May 24, 2012 levels (n=1).