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. 2014 Apr 1;114(7):3381–3465. doi: 10.1021/cr4006654

Figure 28.

Figure 28

Effective potential energy profiles for the proton motion in the Georgievskii–Stuchebrukhov model of EPT. The marked regions are as follows: DW = donor well. In this region, the BO approximation is used and the electronically adiabatic potential for proton motion is approximated as harmonic. DB = donor barrier. This represents the classically forbidden region on the left side of the PES crossing point (i.e., xc in the notation of the reported figure) where the top of the barrier is located. AB = acceptor barrier. AW = acceptor well. Reprinted with permission from ref (195). Copyright 2000 American Institute of Physics.