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. 2014 Apr 1;114(7):3381–3465. doi: 10.1021/cr4006654

Figure 43.

Figure 43

Pathway for two-dimensional tunneling in Cukier’s model for electron–proton transfer reactions. Once the proton is in a position that symmetrizes the effective potential wells for the electronic motion (straight arrow in the left lower corner), the electron tunneling can occur (wavy arrow). Then the proton relaxes to its final position (after Figure 4 in ref (116)).