Table 5.
“Bison Pool” | Octopus Spring | |||||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
13C-Bicarb. | 13C-Formate | 13C-Acetate | 13C-Glucose | 13C-Bicarb. | 13C-Formate | 13C-Acetate | 13C-Glucose | |||||||||||||
t0 | 4 h | 4 h | 4 h | 4 h | t0 | 1.5 h | 1.5 h | 1.5 h | 1.5 h | |||||||||||
ng g−1 | δ13C (‰) | ng g−1 | δ13C (‰) | ng g−1 | δ13C (‰) | ng g−1 | δ13C (‰) | ng g−1 | δ13C (‰) | ng g−1 | δ13C (‰) | ng g−1 | δ13C (‰) | ng g−1 | δ13C (‰) | ng g−1 | δ13C (‰) | ng g−1 | δ13C (‰) | |
FATTY ACIDS | ||||||||||||||||||||
i-C15:0 | 40.1 | −6.6 | 992 | −4.3 | 542 | −6.2 | 1141 | 366 | 1213 | 20.0 | 18.1 | −26.9 | 14.0 | −26.8 | 26.0 | −25.5 | 7.8 | 178 | 14.9 | −20.4 |
ai-C15:0 | 5.9 | −16.8 | 166 | −11.7 | 43.2 | −8.2 | 70.3 | 2283 | 85.4 | 188.7 | − | − | − | − | − | − | − | − | − | − |
C15:0 | 40.8 | −17.4 | 108 | −13.8 | 278 | −16.6 | 59.0 | 1161 | 186 | 14.1 | 23.5 | −20.6 | 4.9 | −21.8 | 18.5 | −22.0 | 7.7 | −2.2 | 15.0 | −20.8 |
i-C16:0 | 252 | −9.2 | 1837 | −7.6 | 977 | −7.5 | 1630 | 389 | 2080 | 25.1 | 45.7 | −24.6 | 34.0 | −25.3 | 56.1 | −24.5 | 21.9 | 150 | 51.6 | −16.8 |
C16:1 | 144 | −26.6 | 484 | −21.1 | 43.2 | −12.3 | 136 | −10.0 | 202 | −17.2 | − | − | − | − | − | − | − | − | − | − |
C16:0 | 1585 | −25.1 | 2854 | −20.9 | 2126 | −18.1 | 1328 | 929 | 1523 | 43.2 | 182 | −25.6 | 169 | −26.7 | 215 | −26.1 | 257 | −18.1 | 195 | −25.3 |
i-C17:0 | 178 | −7.7 | 6044 | −6.3 | 3719 | −6.9 | 5789 | 621 | 6608 | 22.4 | 877 | −26.5 | 930 | −26.4 | 1439 | −25.8 | 570 | 26.4 | 1464 | −24.8 |
ai-C17:0 | 69.0 | −11.0 | 711 | −10.1 | 402 | −7.2 | 581 | 1687 | 845 | 95.4 | 158 | −22.7 | 81.3 | −23.5 | 117 | −21.8 | 74.9 | 89.0 | 151 | −14.5 |
C17:0 | 319 | −16.6 | 333 | −9.6 | 1253 | −15.7 | 300 | 724 | 534 | 9.4 | 101 | −22.0 | 51.5 | −22.7 | 92 | −22.3 | 42.3 | 15.1 | 91.8 | −21.1 |
i-C18:0 | 187 | −10.5 | 709 | −8.0 | 397 | −7.3 | 555 | 905 | 736 | 38.1 | 255 | −25.7 | 194 | −26.6 | 313 | −26.4 | 128 | 24.1 | 325 | −24.5 |
C18:1 | 260 | −23.8 | 1034 | −14.4 | 350 | −13.9 | 689 | 61.1 | 510 | −2.4 | − | − | − | − | − | − | − | − | − | − |
C18:0 | 2019 | −6.4 | 6865 | −1.2 | 4732 | −1.1 | 7953 | 218 | 8182 | 7.5 | 930 | −23.5 | 558 | −23.8 | 911 | −23.3 | 426 | 5.9 | -36 | −22.8 |
i-C19:0 | 368 | −7.3 | 1621 | −7.2 | 955 | −6.5 | 1437 | 624 | 1611 | 0.5 | 969 | −26.5 | 685 | −26.1 | 1122 | −26.1 | 483 | −2.4 | 1108 | −25.7 |
ai-C19:0 | 35.7 | −3.5 | 218 | 0.5 | 76.4 | −1.8 | 272 | 609 | 221 | 26.7 | 37.5 | −25.3 | 27.9 | −25.3 | 39.3 | −22.9 | 20.6 | 44.7 | 43.7 | −22.5 |
cy-C19:0 | 31.2 | −16.4 | 61.6 | −8.4 | 43.2 | −9.9 | 69 | 63.6 | 55.4 | −4.6 | 32.5 | −22.9 | 52.1 | −25.3 | 95.5 | −25.5 | 15.3 | −15.2 | 49.8 | −23.8 |
C19:0 | 174 | −3.2 | 540 | −1.1 | 397 | −2.5 | 641 | 106 | 703 | 1.4 | 172 | −22.6 | 96.8 | −22.8 | 162 | −22.6 | 68.8 | −0.5 | 168 | −22.1 |
iC20:0 | − | − | − | − | − | − | − | − | − | − | 43.9 | −27.1 | 25.0 | −26.7 | 43.0 | −23.4 | 18.6 | 8.7 | 39.9 | −24.7 |
C20:1 | 1054 | −4.4 | 8901 | 4.7 | 2022 | 5.1 | 12966 | 28.7 | 8856 | 5.1 | 20.7 | −23.2 | 32.7 | −29.7 | 63.7 | −23.7 | 34.5 | 23.0 | 23.4 | −21.6 |
C20:0 | 1252 | −2.1 | 3524 | 1.6 | 2628 | 1.1 | 4223 | 68.3 | 4451 | 3.9 | 493 | −23.5 | 318 | −23.7 | 443 | −25.0 | 266 | −17.7 | 448 | −23.2 |
C20:2 | 40.1 | 0.5 | 90.4 | 2.6 | 43.2 | 2.1 | 136 | 32.6 | 123 | 3.6 | 45.0 | −25.5 | 23.6 | −25.9 | 39.0 | −25.0 | 20.6 | 0.8 | 40.9 | −25.0 |
cy-C21:0 | 339 | 0.8 | 1449 | 1.0 | 1332 | 1.0 | 1941 | 7.8 | 2007 | 1.3 | 485 | −23.4 | 756 | −23.9 | 1387 | −23.3 | 212 | −20.9 | 638 | −22.8 |
C22:1 | 5.9 | 2.2 | 539 | 3.2 | 180 | 3.1 | 340 | 24.9 | 659 | 3.3 | − | − | − | − | − | − | − | − | − | − |
C22:0 | 295 | −22.9 | 1315 | −9.2 | 184 | −15.6 | 816 | 18.8 | 1674 | −8.9 | − | − | − | − | − | − | − | − | − | − |
Weighted mean | −6.5 | −3.6 | −4.8 | 268 | 12.8 | −24.8 | −24.8 | −24.8 | 7.1 | −23.8 | ||||||||||
ETHER CLEAVAGE PRODUCTS | ||||||||||||||||||||
C18:0 | 609 | 1.7 | 131 | 1.1 | 814 | −1.0 | 28.1 | 11.0 | 43.5 | 2.7 | 1385 | −23.2 | 1207 | −23.6 | 1269 | −23.3 | 429 | −20.1 | 1628 | −25.0 |
C19:0 | 167 | −1.5 | 133 | −1.5 | 100 | −6.8 | 33.8 | 129.6 | 14.6 | 3.4 | 385 | −23.8 | 254 | −22.1 | 310 | −24.0 | 300 | −22.0 | 394 | −24.7 |
C20:1 | 720 | 3.7 | 997 | 5.1 | 852 | 2.7 | 398 | 103.9 | 311.6 | 9.3 | − | − | 88.6 | − | 91.2 | − | 38.0 | − | 116 | − |
C20:0 | 2202 | 2.1 | 1955 | 2.0 | 506 | 1.3 | 909 | 5.7 | 873 | 3.3 | 1318 | −23.3 | 1946 | −22.6 | 1276 | −23.1 | 699 | −23.4 | 1481 | −23.0 |
C21:1 | 47.4 | −2.3 | 146 | −2.5 | − | − | 66.7 | 14.0 | 57.0 | − | 565 | −24.8 | 570 | −24.8 | 495 | −24.6 | 314 | −27.0 | 632 | −26.4 |
Phytane | 195 | −14.0 | 35.2 | −8.4 | 45.5 | −10.9 | 11.9 | 20.9 | 24.1 | −6.3 | 78.7 | −25.0 | 200 | −25.7 | 73.8 | −26.7 | 25.6 | 223.0 | 120 | −24.2 |
Biphytane 0 | 203 | −8.6 | 542 | −8.9 | 905 | −9.8 | 483 | −10.1 | 476 | −10.1 | 1208 | −27.2 | 1689 | −27.6 | 990 | −27.1 | 736 | −10.3 | 1740 | −27.0 |
Biphytane 1 | 168 | −10.1 | 902 | −11.7 | 1298 | −10.8 | 777 | −11.7 | 907 | −10.7 | 537 | −24.1 | 610 | −24.2 | 354 | −22.9 | 264 | −22.9 | 627 | −23.5 |
Biphytane 2 | 266 | −13.0 | 1753 | −13.6 | 2447 | −13.4 | 1524 | −14.1 | 1174 | −13.4 | 468 | −20.2 | 461 | −22.8 | 286 | −19.8 | 219 | −19.1 | 541 | −19.4 |
Weighted mean | −1.2 | −5.7 | −8.2 | −0.9 | −0.4 | −25.3 | −24.5 | −25.0 | −4.1 | −25.4 |
nd, no data.