Table 2.
DOPC 1H chemical shifts (ppm) of the preparations (a) DOPC, (b) DOPC/cholesterol, (c) DOPC/TCV-116, and (d) DOPC/cholesterol/TCV-116 obtained at 27 °C using 850 MHz Bruker spectrometer.
| Atoms or groups | DOPC/H2O | DOPC/D2O | Literature data (DOPC/H2O) [10] |
DOPC/cholest. (x = 0.30) |
DOPC/cholest. (x = 0.15) |
Literature data (x = 0.33) (H2O) [10] |
DOPC/TCV-116 (x = 0.10) |
DOPC/TCV-116 (x = 0.20) |
[DOPC/CHOL (x = 0.30)]/ TCV-116 (x = 0.20) |
[DOPC/CHOL (x = 0.15)]/ (x = 0.20) |
|---|---|---|---|---|---|---|---|---|---|---|
| Lα | 4.29 | 4.35 | 4.28 | 4.35 | 4.36 | 4.28 | 4.33 | 4.32 | 4.33 | 4.33 |
| Lβ | 3.68 | 3.74 | 3.70 | 3.73 | 3.75 | 3.70 | 3.72 | 3.71 | 3.72 | 3.71 |
| Lυ | 3.24 | 3.30 | 3.26 | 3.29 | 3.31 | 3.26 | 3.28 | 3.27 | 3.28 | 3.27 |
| L1′ | 4.22 | 4.29 | 4.24 | 4.29 | 4.30 | 4.24 | 4.25 | 4.24 | 4.27 | 4.25 |
| L2′ | 5.29 | |||||||||
| L9 | 5.33 | |||||||||
| L10 | 5.30 | 5.38 | 5.29 | 5.36 | 5.38 | 5.31 | 5.36 | 5.35 | 5.36 | 5.36 |
| L3′ | 4.00 | 4.07 | 4.01 | 4.07 | 4.07 | 4.01 | 4.04 | 4.03 | 4.05 | 4.04 |
| LCO-sn1 | 4.43 | 4.50 | 4.46 | 4.49 | 4.50 | 4.42 | 4.46 | 4.45 | 4.47 | 4.46 |
| LCO-sn2 | 2.41 | 2.47 | 2.44 | 2.47 | 2.48, | 2.48 | 2.41 | 2.39 | 2.42, 2.37 |
2.41, 2.36 |
| L2 | 2.34, 2.31 |
2.40, 2.39 |
2.36 | 2.41, 2.36 |
2.42, 2.37 |
2.36 | 2.35, 2.31 |
2.33, 2.30 |
2.32 | 2.31 |
| L3 | 1.60 | 1.66 | 1.63 | 1.66 | 1.67 | 1.61 | 1.61 | 1.59 | 1.62 | 1.61 |
| L4-7, L12-17 | 1.29 | 1.36 | 1.32 | 1.36 | 1.37 | 1.39, 1.34, 1.30 |
1.34 | 1.33 | 1.35 | 1.34 |
| L8/L11 | 2.01 | 2.08 | 2.01 | 2.08 | 2.09 | 2.03, 2.02 |
2.06 | 2.05 | 2.07 | 2.06 |
| L18 | 0.88 | 0.95 | 0.89 | 0.94 | 0.96 | 0.89 | 0.94 | 0.93 | 0.94 | 0.94 |