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. 2014 Nov 10;6(2):1115–1119. doi: 10.1039/c4sc03106g

Table 2. Reaction with benzyl diethyl phosphate, a less reactive electrophile a .

Inline graphic
Entry Co(Pc) (mol %) T (°C) Yield b
1 3 rt ND c
2 3 40 ND c
3 1 80 3 c , d
4 3 80 36 c , d
5 6 80 (70) d

aReactions run at 0.25 M in DMA using pre-formed 6 for 15–22 h. See ESI.

bYield of 3a′ from GC area% data. Yields in parentheses are isolated yields of purified product.

cSignificant amounts of starting materials remain.

dOnly byproduct observed by GC analysis was small amounts of benzene from hydrodehalogenation of Ph-Br.