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. Author manuscript; available in PMC: 2015 Aug 11.
Published in final edited form as: Adv Synth Catal. 2014 Jul 30;356(11-12):2517–2524. doi: 10.1002/adsc.201400679

Table 2.

Laboratory-scale Reactions Using the top HTE Conditions.

graphic file with name nihms640057u2.jpg
entry base Pd source solvent assay yield (%)a
1 LiN(SiMe3)2 [PdCl(allyl)]2 THF 61
2 LiN(SiMe3)2 PdCl2(cod) DME 57
3 LiN(SiMe3)2 PdCl2(cod) toluene 35
4 LiN(SiMe3)2 PdCl2 toluene 0
5 NaN(SiMe3)2 Pd(OAc)2 CPME 56
6 NaN(SiMe3)2 PdCl2(cod) CPME 58
7 NaN(SiMe3)2 [PdCl(allyl)]2 toluene 45
a

Yields determined by 1H NMR analysis of crude mixture with CH2Br2 as internal standard.