. 2014 Nov 12;6(2):1219–1224. doi: 10.1039/c4sc02610a

Table 2. [Co(P3)]-catalyzed asymmetric C–H alkylation of α-methoxycarbonyl-α-diazosulfone compounds ^a .

^aSyntheses of catalysts and diazo compounds are summarized in ESI;¹⁵ reactions were carried out at room temperature for 72 h using [Co(P3)] under N₂; isolated yields; the trans : cis diastereomeric ratios were determined by ¹H-NMR; enantiomeric excesses were determined by chiral HPLC.

^b[2S,3R] absolute configuration determined by anomalous-dispersion effects in X-ray diffraction measurements on a crystal.

^c5 mol% catalyst used.

^dPhF used as solvent.

Table 2. [Co(P3)]-catalyzed asymmetric C–H alkylation of α-methoxycarbonyl-α-diazosulfone compounds a .

Table 2. [Co(P3)]-catalyzed asymmetric C–H alkylation of α-methoxycarbonyl-α-diazosulfone compounds ^a .