Table 1.

Synthesis of α-functionalized alkyl(MIDA)boronates^a

entry	NuH	product	yield (%)
1b	6a	7a	99
2b	6b	7b	94
3	6c	7c	97
4c	6d	7d	91
5	6e	7e	99
6	6f	7f	78
7	6g	7g	98
8	6h	7h	96
9	6i	7i	85
10	6j	7j	92

^aUnless otherwise noted, reactions were conducted with alcohol (1.0 equiv.), 1.0 equiv. of acidic pronucleophile, 1.2 equiv. of triphenylphosphine, and 1.2 equiv. of DIAD in THF at 23 °C for 30 min.

^b1.5 equiv. of acidic pronucleophile, 1.5 equiv. of triphenylphosphine, and 1.5 equiv. of DIAD were used. Reaction time: 30 min. Temp.: 23 °C.

^c2.0 equiv. of acidic pronucleophile, 1.5 equiv. of triphenylphosphine, and 1.5 equiv. of DIAD were used. Reaction time: 12 h. Temp.: 23 °C.