. 2015 Jan 16;54(4):1535–1542. doi: 10.1021/ic502535f

Table 2. SKIE Values [k₂(H₂O)/k₂(D₂O)] of Fe^V(O) for Toluene Oxidation in Various Mixtures of H₂O and D₂O in CH₃CN.

H₂O or D₂O (%)	k₂ in H₂O (M^–1 s^–1)	k₂ in D₂O (M^–1 s^–1)	k₂(H₂O)/k₂(D₂O)
10	0.31	0.21	1.5
30	0.47	0.33	1.4
50	1.4	0.91	1.5
70	19.6	14.0	1.4

Table 2. SKIE Values [k2(H2O)/k2(D2O)] of FeV(O) for Toluene Oxidation in Various Mixtures of H2O and D2O in CH3CN.