Table 1. 1H (600 MHz) and 13C (100 MHz) NMR Data of 1 and 2 in CD3OD.
1 |
2 |
|||
---|---|---|---|---|
no. | δH, mult (J, Hz) | δC | δH, mult (J, Hz) | δC |
2 | 7.21, s | 125.7, CH | 7.19, s | 124.6, CH |
3 | 111.9, C | 111.1, C | ||
4 | 7.62, d (8.5) | 120.5, CH | 7.63, d (7.9) | 119.3, CH |
5 | 6.97, dd (8.5, 1.8) | 120.2, CH | 7.00, t (7.3) | 119.7, CH |
6 | 128.2, C | 7.08, t (7.3) | 122.3, CH | |
7 | 7.31, d (1.8) | 111.5, CH | 7.32, d (8.1) | 112.2, CH |
8 | 138.3, C | 138.0, C | ||
9 | 127.6, C | 128.8, C | ||
10 | 3.43, dd (14.8, 4.6) 3.19, dd (14.8, 8.8) | 28.3, CH2 | 3.41, dd (14.8, 5.0) 3.23, dd (14.8, 8.6) | 28.4, CH2 |
11 | 4.87, dd (8.8, 4.6) | 55.0, CH | 4.93, dd (8.6, 5.0) | 55.1, CH |
13 | 170.3, C | 170.3, C | ||
14 | 127.5, C | 127.6, C | ||
15 | 154.3, C | 154.4, C | ||
16 | 6.66, d (8.8) | 115.5, CH | 6.66, d (8.8) | 115.5, CH |
17 | 7.16, d (8.8) | 131.2, CH | 7.16, d (8.7) | 131.2, CH |
18 | 125.6, C | 125.6, C | ||
19 | 135.2, C | 135.2, C | ||
20 | 175.4, C | 175.5, C | ||
21 | 2.07, s | 17.1, CH3 | 2.06, s | 17.0, CH3 |