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. 2014 Sep 30;47(19):6911–6918. doi: 10.1021/ma501258c

Table 1. Molecular Weights and Polydispersity Indices (PDIs) of PDCs.

polymer theor Mw Mn(NMR)a Mn(GPC)b PDIc
PCL3.5K-G3-PEG600-NH2 9297 7075 d d
PCL3.5K-G3-PEG600-Ac 9505 7313 8020 1.052
PCL3.5K-G3-PEG600-COOH 9521 7568 7998 1.303
PCL3.5K-G3-PEG600-Rhod 9755 6839 7538 1.164
a

Number-averaged molecular weight, Mn, estimated by 1H NMR.

b

Measured by GPC using dn/dc values.

c

Calculated by weight-average molecular weights divided by number-average molecular weights using the data obtained by GPC.

d

Not measured due to the limited solubility of amine-terminated PDC in THF.