Table 1. 13C NMR data for antiaritoxioside A-G (1–7) and antiarotoxinin B (8).
Carbon | 1‡ | 2‡ | 3‡ | 4‡ | 5 | 6 | 7‡ | 8 |
---|---|---|---|---|---|---|---|---|
1 | 36.3 | 26.9 | 25.3 | 26.9 | 26.7 | 22.0 | 23.6 | 25.8 |
2 | 22.4 | 28.7 | 27.4 | 28.6 | 27.9 | 26.4 | 26.8 | 28.6 |
3 | 72.9 | 73.9 | 73.8 | 73.8 | 73.2 | 72.3 | 74.1 | 67.8 |
4 | 32.1 | 35.6 | 34.8 | 35.6 | 35.1 | 30.0 | 36.1 | 36.1 |
5 | 72.9 | 74.7 | 73.1 | 74.2 | 74.3 | 30.4 | 73.4 | 74.5 |
6 | 43.3 | 35.8 | 35.1 | 35.9 | 36.5 | 33.2 | 40.8 | 37.8 |
7 | 28.4 | 24.3 | 24.5 | 24.8 | 24.7 | 26.0 | 21.3 | 24.4 |
8 | 42.3 | 40.7 | 41.3 | 40.4 | 40.4 | 48.2 | 41.2 | 39.0 |
9 | 41.0 | 40.2 | 39.4 | 37.5 | 37.7 | 42.0 | 37.3 | 40.0 |
10 | 55.7 | 74.4 | 74.4 | 74.7 | 74.4 | 34.0 | 39.2 | 41.3 |
11 | 23.5 | 21.6 | 22.8 | 30.8 | 30.7 | 22.1 | 26.1 | 22.0 |
12 | 39.9 | 40.0 | 40.4 | 74.7 | 74.7 | 39.7 | 31.4 | 40.3 |
13 | 50.2 | 50.1 | 50.3 | 56.7 | 56.9 | 50.1 | 51.9 | 47.8 |
14 | 84.8 | 84.6 | 85.0 | 85.0 | 85.1 | 83.8 | 86.7 | 83.8 |
15 | 33.4 | 33.0 | 33.0 | 33.4 | 33.4 | 32.2 | 33.7 | 33.1 |
16 | 27.2 | 27.5 | 27.2 | 27.9 | 29.2 | 22.1 | 34.3 | 19.0 |
17 | 51.5 | 51.3 | 51.3 | 46.4 | 46.2 | 51.4 | 87.8 | 51.5 |
18 | 16.3 | 16.3 | 16.3 | 10.3 | 10.3 | 16.4 | 13.1 | 15.5 |
19 | 176.7 | 17.0 | 17.4 | |||||
20 | 176.1 | 176.3 | 176.4 | 176.7 | 176.8 | 176.0 | 174.0 | 71.1 |
21 | 73.8 | 73.8 | 73.8 | 74.0 | 74.1 | 73.6 | 73.8 | 65.8 |
22 | 117.6 | 117.7 | 117.6 | 117.5 | 117.4 | 117.6 | 116.6 | |
23 | 174.6 | 174.8 | 174.6 | 174.7 | 174.8 | 174.5 | 173.2 | |
1′ | 99.8 | 100.8 | 99.3 | 100.7 | 99.4 | 99.8 | 99.8 | |
2′ | 72.7 | 72.6 | 72.2 | 72.6 | 69.8 | 72.9 | 69.6 | |
3′ | 72.8 | 73.0 | 73.1 | 72.9 | 73.6 | 72.9 | 73.8 | |
4′ | 74.3 | 73.9 | 73.8 | 73.7 | 73.7 | 74.1 | 73.3 | |
5′ | 69.9 | 70.7 | 70.8 | 70.7 | 70.0 | 70.0 | 70.0 | |
6′ | 18.6 | 18.6 | 18.8 | 18.6 | 17.0 | 18.6 | 17.3 |
δ Value in pyridine-d5 (100 MHz).
δ Value in pyridine-d5 (75 MHz).