Table 11. Sequences of 19-residue peptaibiotics detected in the plate culture of Hypocrea minutispora.

No.	tR [min]	[M+ H]+		Residuea
				1	2	3	4	5	6	7	8	9	10	11	12	13	14	15	16	17	18	19
64	36.1–36.3	1832.1060	Ac	Aib	Ala	Aib	Ala	Aib	Gln	Aib	Lxx	Aib	Gly	Lxx	Aib	Pro	Vxx	Aib	Aib	Gln	Gln	Vxxol
65	37.3–37.5	1832.1025	Ac	Aib	Ala	Aib	Gly	Aib	Gln	Aib	Lxx	Aib	Gly	Lxx	Aib	Pro	Vxx	Aib	Vxx	Gln	Gln	Vxxol
66	37.5–37.9	1846.1196	Ac	Aib	Ala	Aib	Ala	Aib	Gln	Aib	Lxx	Aib	Gly	Vxx	Aib	Pro	Vxx	Aib	Vxx	Gln	Gln	Lxxol
57	37.8–38.0	1846.1199	Ac	Aib	Ala	Aib	Ala	Aib	Gln	Aib	Lxx	Aib	Gly	Lxx	Aib	Pro	Vxx	Aib	Aib	Gln	Gln	Lxxol
67	38.6–38.7	1847.1135	Ac	Aib	Ala	Aib	Ala	Aib	Gln	Aib	Lxx	Aib	Gly	Lxx	Aib	Pro	Vxx	Aib	Aib	Glu	Gln	Lxxol
59	39.0–39.2	1860.1318	Ac	Aib	Ala	Aib	Ala	Aib	Gln	Aib	Lxx	Aib	Gly	Lxx	Aib	Pro	Vxx	Aib	Vxx	Gln	Gln	Lxxol
60	39.8–40.0	1861.1271	Ac	Aib	Ala	Aib	Ala	Aib	Gln	Aib	Lxx	Aib	Gly	Lxx	Aib	Pro	Vxx	Aib	Vxx	Glu	Gln	Lxxol
68	40.4–40.6	1874.1492	Ac	Aib	Ala	Aib	Ala	Aib	Gln	Aib	Lxx	Aib	Gly	Lxx	Aib	Pro	Lxx	Aib	Vxx	Gln	Gln	Lxxol
61	40.6–40.9	1874.1554	Ac	Aib	Ala	Aib	Ala	Vxx	Gln	Aib	Lxx	Aib	Gly	Lxx	Aib	Pro	Vxx	Aib	Vxx	Gln	Gln	Lxxol

No.	Compound identical or positionally isomeric with	Ref.
64	Minutisporin-9 (pos. 1, 6–10, 12–19; [Pro]2→ [Ala]2, [Aib]11→[Lxx]11 and deletion of [Aib]5: cf. stilboflavin B-5)	Jaworski and Brückner 2001b
65	Minutisporin-10 (positional isomer of 64: [Ala]4→[Gly]4, [Aib]16→[Vxx]16)
66	Minutisporin-11 (positional isomer of 57: [Lxx]11→[Vxx]11, [Aib]16→[Vxx]16)
57	Minutisporin-2
67	Minutisporin-12 (positional isomer of 57: [Gln]17→[Glu]17 and of 56: [Ala]4→[Gly]4, [Aib]16→[Vxx]16)
59	Minutisporin-4
60	Minutisporin-5
68	Minutisporin-13 (positional isomer of 61: [Aib]5→[Vxx]5)
61	Minutisporin-6

^aVariable residues are underlined in the table header. Minor sequence variants are underlined in the sequences. This applies to all sequence tables