Table 3.
Peak no.a |
Components | Retention index | Peak area (%)d |
|
---|---|---|---|---|
Polarb | Apolarc | |||
Monoterpene hydrocarbons | (19.66) | |||
1 | Tricyclene | 1009 | 920 | 0.18 |
2 | α-Pinene | 1027 | 933 | 4.97 |
3 | α-Thujene | 1030 | 925 | 0.23 |
4 | Camphene | 1070 | 945 | 4.19 |
5 | β-Pinene | 1110 | 970 | 4.45 |
6 | Sabinene | 1123 | 966 | 0.61 |
10 | Myrcene | 1167 | 984 | 0.92 |
11 | α-Terpinene | 1181 | 1007 | 0.48 |
13 | Limonene | 1199 | 1020 | 0.65 |
16 | cis-β-Ocimene | 1239 | 1029 | 0.87 |
17 | γ-Terpinene | 1249 | 1050 | 0.47 |
18 | p-Cymene | 1276 | 1022 | 1.34 |
19 | Terpinolene | 1286 | 1078 | 0.30 |
Oxygenated monoterpenes | (47.23) | |||
12 | 2,3-Dehydro-1,8-cineole | 1191 | 976 | 0.05 |
14 | 1,8-Cineole | 1212 | 1020 | 4.52 |
22 | α-Thujone | 1427 | 1090 | 5.46 |
23 | β-Thujone | 1441 | 1096 | 1.04 |
28 | Camphor | 1518 | 1124 | 20.89 |
30 | Linalool | 1537 | 1101 | 0.10 |
31 | trans-Sabinene hydrate | 1562 | 1051 | 0.40 |
32 | trans-Chrysanthenyl acetate | 1569 | 1186 | 0.46 |
33 | Bornyl acetate | 1576 | 1268 | 0.69 |
35 | Terpinen-4-ol | 1599 | 1165 | 0.72 |
36 | Lavandulyl acetate | 1608 | — | 0.08 |
37 | Myrtenal | 1621 | 1167 | 0.15 |
38 | Umbellulone | 1639 | 1149 | 0.28 |
39 | Pinocarveol | 1651 | 1124 | 0.29 |
40 | p-Mentha-1,5-dien-8-ol | 1662 | 1169 | 0.60 |
43 | α-Terpineol | 1697 | 1174 | 0.38 |
44 | Borneol | 1701 | 1146 | 1.94 |
48 | Piperitone | 1725 | 1224 | 5.27 |
49 | Carvone | 1731 | 1212 | 1.14 |
50 | cis-Chrysanthenol | 1761 | 1157 | 2.07 |
53 | Myrtenol | 1795 | 1179 | 0.32 |
54 | trans-Carveol | 1833 | 1181 | 0.09 |
55 | Geraniol | 1852 | — | 0.07 |
56 | Geranyl acetone | 1854 | — | 0.08 |
57 | cis-Carveol | 1860 | 1196 | 0.14 |
Sesquiterpene hydrocarbons | 12.51 | |||
25 | α-Guaiene | 1470 | — | 0.09 |
27 | α-Copaene | 1493 | 1370 | 0.32 |
29 | Berkheyaradulen | 1527 | 1377 | 0.19 |
34 | β-Caryophyllene | 1590 | 1412 | 5.71 |
41 | cis-β-Farnesene | 1671 | — | 0.38 |
42 | β-Selinene | 1676 | 1488 | 0.15 |
45 | epi-Sesquiphellandrene | 1707 | — | 5.16 |
46 | Widdrene | 1710 | — | 0.09 |
47 | Zingiberene | 1714 | 1496 | 0.42 |
51 | ar-Curcumene | 1780 | 1484 | 0.28 |
Oxygenated Sesquiterpenes | (4.44) | |||
58 | Caryophyllene oxide | 1975 | 1561 | 2.08 |
59 | Viridiflorol | 2042 | 1569 | 0.10 |
60 | Nerolidol | 2049 | 1555 | 0.38 |
61 | Elemol | 2072 | — | 0.40 |
62 | Spathulenol | 2118 | 1563 | 0.42 |
64 | Torreyol | 2167 | 1606 | 0.15 |
67 | epi-Globulol | 2217 | 1589 | 0.44 |
68 | Farnesol | 2244 | 1688 | 0.03 |
70 | α-Costol | 2301 | — | 0.29 |
71 | Caryophyllenol II | 2349 | — | 0.07 |
72 | Farnesol (isomer) | 2353 | 1704 | 0.08 |
Others | (1.58) | |||
5 | n-Hexanal | 1087 | 835 | 0.07 |
8 | Butyl benzene | 1126 | 938 | 0.11 |
9 | 2-Methylpropylbenzene | 1133 | 1050 | 0.14 |
15 | 2-Pentyl furan | 1236 | 981 | 0.04 |
20 | 6-Methyl-5-hepten-2-one | 1341 | — | 0.06 |
21 | n-Hexanol | 1356 | 882 | 0.10 |
24 | 1-Octen-3-ol | 1454 | 966 | 0.21 |
26 | 2,2,4-Trimethyl-2-cyclohexene carbaldehyde | 1474 | 1040 | 0.04 |
52 | Methyl salicylate | 1789 | 1169 | 0.07 |
63 | Eugenol | 2164 | 1327 | 0.29 |
65 | Thymol | 2185 | 1275 | 0.34 |
66 | Carvacrol | 2212 | 1275 | 0.05 |
69 | Decanoic acid | 2263 | — | 0.06 |
| ||||
Total identified | (85.42) |
aNumbering refers to the elution order on Supelcowax 10 column.
bRetention index on polar Supelcowax 10 column.
cRetention index on apolar SPB-1 column.
dPeak area percentage is based on polar Supelcowax 10 column, and values represent averages of three determinations.