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Figure Inverse entry of substrate is consistent with cavity depth in 15-LOX-2 and 5-LOX. (A) A schematic depicting how the products 15S-HPETE and 5S-HPETE can be explained by substrate entry in 15-LOX-2 as “tail-first” and that in 5-LOX as “head-first.” (B) The cavity depths in 15-LOX-2 (flesh) and 5-LOX (yellow) are consistent with this interpretation. The innermost part of the 5-LOX cavity should accommodate a carboxyl, rather than hydrocarbon.
