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. 2015 Feb 27;11:294–301. doi: 10.3762/bjoc.11.34

Table 1.

Effect of temperature onto yield and stereoselectivity of the electrochemical reduction of 7a on a lead cathode.

Entrya T [°C] yieldb [%] c.e.c [%] drd [8a:8b]

1 60 33 13 6.2
2 40 85 34 5.4
3 20 93 38 5.2

aCatholyte: 0.5% MTES and 2% H2SO4 in MeOH, current density: 12.5 mA cm–2, passed charge: 10 F mol–1, anode: platinum; byield determined by GC (internal standard); cc.e. = current efficiency; dratio determined by NMR spectroscopy.