Table 1.
Reaction of 3a-X (X = Br, I) with different bases.a
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| % Yield of productb | |||||||
| X = Br | X = I | ||||||
| Base | 4a-Br | 5a-Br | 6a | 4a-Ir | 5a-I | 6a | |
| Et3N/CH2Cl2 | 83 | ND | ND | 85 | ND | 1 | |
| NaOH/H2O | ND | 89 | 2 | ND | 84 | 1 | |
| NaOMe/MeOH | ND | ND | 95 | ND | ND | 96 | |
aThe electrolysis was carried out using 1.3 equiv of Bu4NBr or Bu4NI (based on the alkene which was added after electrolysis) with 2.1 F/mol of electricity based on Bu4NBr or Bu4NI. bYields were determined by GC.
