Table 1.
Peak | Observed m/z |
Theory m/z |
Mass | Charge | Composition | Proposed structure | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
Hex | HexNAc | Fuc | Xyl | NeuAc | NeuGc | Kdn | ||||||
1 | 753.36 | 753.36 | 2191.12 | 3 | 4 | 4 | 2 | 0 | 0 | 0 | 0 | |
753.38 | 1482.75 | 2 | 3 | 2 | 1 | 1 | 0 | 0 | 0 | |||
752.82 | 1459.66 | 2 | 3 | 3 | 0 | 0 | 0 | 0 | 0 | |||
752.37 | 2210.12 | 3 | 7 | 3 | 0 | 0 | 0 | 0 | 0 | |||
2 | 825.82 | 825.73 | 2408.22 | 3 | 5 | 4 | 0 | 0 | 1 | 0 | 0 | |
825.73 | 2408.22 | 3 | 4 | 4 | 1 | 0 | 0 | 1 | 0 | |||
826.73 | 2411.22 | 3 | 6 | 4 | 1 | 1 | 0 | 0 | 0 | |||
826.75 | 2455.24 | 3 | 7 | 4 | 0 | 0 | 0 | 0 | 0 | |||
826.77 | 2477.27 | 3 | 3 | 6 | 2 | 0 | 0 | 0 | 0 | |||
3 | 955.73 | 955.83 | 2864.47 | 3 | 3 | 9 | 0 | 0 | 0 | 0 | 0 | |
955.46 | 2797.42 | 3 | 4 | 5 | 2 | 0 | 1 | 0 | 0 | |||
955.45 | 1908.88 | 2 | 4 | 4 | 0 | 0 | 0 | 0 | 0 | |||
956.12 | 2799.40 | 3 | 5 | 4 | 0 | 0 | 1 | 1 | 0 | |||
956.14 | 2799.44 | 3 | 5 | 5 | 1 | 0 | 0 | 1 | 0 | |||
956.49 | 2844.45 | 3 | 6 | 5 | 2 | 0 | 0 | 0 | 0 |
|
||
4 | 999.27 | 999.50 | 2973.49 | 3 | 5 | 4 | 1 | 0 | 1 | 1 | 0 | |
999.50 | 2973.49 | 3 | 6 | 4 | 0 | 0 | 2 | 0 | 0 | |||
999.82 | 2930.49 | 3 | 5 | 4 | 3 | 0 | 1 | 0 | 0 | |||
1000.00 | 1976.01 | 2 | 5 | 3 | 1 | 0 | 0 | 0 | 0 | |||
998.50 | 1973.01 | 2 | 3 | 4 | 1 | 1 | 0 | 0 | 0 | |||
998.49 | 2926.50 | 2 | 4 | 7 | 2 | 0 | 0 | 0 | 0 | |||
5 | 1080.82 | 1081.21 | 3218.61 | 3 | 6 | 5 | 0 | 0 | 2 | 0 | 0 | |
1081.54 | 2139.08 | 2 | 7 | 2 | 1 | 0 | 0 | 0 | 0 | |||
1081.56 | 2161.11 | 2 | 3 | 4 | 3 | 0 | 0 | 0 | 0 | |||
1079.87 | 3214.61 | 3 | 6 | 5 | 4 | 0 | 0 | 0 | 0 | |||
6 | 1129.27 | 1129.23 | 3362.69 | 3 | 5 | 5 | 2 | 0 | 2 | 0 | 0 | |
1129.91 | 3364.71 | 3 | 7 | 7 | 1 | 0 | 0 | 0 | 0 | |||
7 | 1238.27 | 1238.28 | 3667.84 | 3 | 7 | 6 | 0 | 0 | 2 | 0 | 0 | |
1238.09 | 2474.16 | 2 | 5 | 4 | 0 | 0 | 1 | 0 | 0 | |||
1238.63 | 3712.85 | 3 | 7 | 4 | 0 | 0 | 3 | 0 | 0 | |||
1238.64 | 3712.88 | 3 | 7 | 7 | 3 | 0 | 0 | 0 | 0 | |||
1238.96 | 3669.89 | 3 | 6 | 5 | 1 | 0 | 0 | 3 | 0 | |||
1237.62 | 3687.86 | 3 | 9 | 6 | 1 | 1 | 0 | 0 | 0 | |||
1237.61 | 3665.83 | 3 | 5 | 4 | 1 | 0 | 4 | 0 | 0 | |||
8 | 1156.82 | 1156.93 | 3467.76 | 3 | 7 | 6 | 3 | 0 | 0 | 0 | 0 | |
9 | 1266.18 | 1265.98 | 3794.90 | 3 | 5 | 6 | 1 | 0 | 3 | 0 | 0 | |
1265.97 | 3772.91 | 3 | 9 | 7 | 1 | 0 | 0 | 0 | 0 | |||
1265.64 | 2507.29 | 2 | 4 | 6 | 1 | 0 | 0 | 0 | 0 | |||
1266.95 | 3731.89 | 3 | 10 | 6 | 1 | 0 | 0 | 0 | 0 | |||
1266.96 | 3753.88 | 3 | 6 | 5 | 1 | 0 | 3 | 0 | 0 | |||
10 | 1306.91 | 1307.17 | 2612.31 | 2 | 6 | 4 | 0 | 0 | 1 | 0 | 0 | |
1307.17 | 2612.31 | 2 | 5 | 4 | 1 | 0 | 0 | 1 | 0 | |||
1307.64 | 3875.93 | 3 | 6 | 6 | 1 | 0 | 0 | 0 | 3 | |||
1307.65 | 2569.31 | 2 | 5 | 4 | 3 | 0 | 0 | 0 | 0 | |||
1306.18 | 2610.34 | 2 | 4 | 5 | 3 | 0 | 0 | 0 | 0 | |||
11 | 1346.45 | 1347.11 | 2648.25 | 2 | 5 | 4 | 1 | 0 | 1 | 0 | 0 | |
1347.18 | 2670.36 | 2 | 6 | 5 | 1 | 0 | 0 | 0 | 0 | |||
1345.67 | 1322.68 | 1 | 3 | 2 | 1 | 0 | 0 | 0 | 0 | |||
1345.65 | 2689.28 | 2 | 4 | 5 | 1 | 0 | 1 | 0 | 0 | |||
12 | 1615.82 | 1614.81 | 1590.81 | 2 | 6 | 5 | 2 | 0 | 1 | 0 | 0 |