Table 1.
VOC | RT [min] | Measurement range [μg m−3] | Equation of the calibration curve | Correlation coefficient | Limit of detection [μg m−3] | Limit of quantification [μg m−3] | Precision [%] |
---|---|---|---|---|---|---|---|
Benzene | 2.78 | 0.4–11 | 167,225x + 418,483 | 0.9988 | 0.01 | 0.03 | 5.99 |
11–44 | 197,294x + 157,024 | 0.9989 | |||||
Trichloroethylene | 3.27 | 0.4–11 | 442,760x + 621,235 | 0.9999 | 0.02 | 0.05 | 6.84 |
Toluene | 4.58 | 0.4–11 | 721,328x + 56,108 | 0.9999 | 0.01 | 0.03 | 7.32 |
11–44 | 654,444x − 8,413,649 | 0.9998 | |||||
46.3–370.7 | 902,973x + 1,861,071 | 0.9992 | |||||
Tetrachloroethylene | 5.79 | 0.4–11 | 969,296x + 384,238 | 0.9987 | 0.007 | 0.02 | 5.57 |
Butyl acetate | 6.06 | 0.46–27.8 | 239,743x−60,438 | 0.9994 | 0.002 | 0.008 | 7.82 |
Chlorobenzene | 6.97 | 0.4–11 | 526,266x + 668,139 | 0.9982 | 0.01 | 0.04 | 5.70 |
Ethylbenzene | 7.47 | 0.4–11 | 966,381x + 2,083,209 | 0.9993 | 0.007 | 0.02 | 6.30 |
11–44 | 1,140,611x−2,068,484 | 0.9996 | |||||
m-, p-Xylene | 7.74 | 0.4–11 | 1,774,148x + 2,881,217 | 0.9994 | 0.01 | 0.03 | 7.04 |
11–44 | 1,215,289x + 13,904,661 | 0.9987 | |||||
o-Xylene | 8.45 | 0.4–11 | 1,818,879x + 1,567,847 | 0.9988 | 0.007 | 0.02 | 5.50 |
11–44 | 1,230,227x + 42,782,952 | 0.9999 | |||||
Styrene | 8.59 | 0.4–11 | 675,856x + 1,137,873 | 0.9996 | 0.01 | 0.03 | 6.38 |
11–44 | 715,852x−6,354,713 | 0.9989 | |||||
1,3,5-Trimethylbenzenea | 11.27 | 0.4–11 | 721,328x + 56,108 | 0.9999 | 0.01 | 0.03 | 7.32 |
11–44 | 654,444x − 8,413,649 | 0.9998 | |||||
α-Methylstyrenea | 11.80 | 46.3–370.7 | 902,973x + 1,861,071 | 0.9992 | 0.01 | 0.03 | 7.32 |
1,2,3-Trimethylbenzenea | 12.17 | 0.4–11 | 721,328x + 56,108 | 0.9999 | 0.01 | 0.03 | 7.32 |
11–44 | 654,444x−8,413,649 | 0.9998 | |||||
1,2,4-Trimethylbenzenea | 13.20 | 0.4–11 | 721,328x + 56,108 | 0.9999 | 0.01 | 0.03 | 7.32 |
11–44 | 654,444x−8,413,649 | 0.9998 | |||||
1,4-Dichlorobenzene | 12.61 | 0.4–11 | 989,383x + 1,243,438 | 0.9998 | 0.007 | 0.021 | 6.42 |
Butylcyclohexanea | 13.48 | 46.3–370.7 | 902,973x + 1,861,071 | 0.9992 | 0.01 | 0.03 | 7.32 |
1,2-Dichlorobenzene | 14.17 | 0.4–11 | 156,645x + 233,184 | 0.9999 | 0.004 | 0.012 | 6.13 |
Decamethylcyclopentasiloxanea | 17.76 | 0.4–11 | 721,328x + 56,108 | 0.9999 | 0.01 | 0.03 | 7.32 |
11–44 | 654,444x − 8,413,649 | 0.9998 | |||||
46.3–370.7 | 902,973x + 1,861,071 | 0.9992 | |||||
1,2,4-Trichlorobenzene | 18.37 | 0.4–11 | 689,137x + 2,098,565 | 0.9996 | 0.01 | 0.03 | 5.83 |
Naphthalene | 18.54 | 0.4–11 | 1,373,157x + 1,955,718 | 0.9995 | 0.005 | 0.01 | 5.32 |
11–44 | 1,393,397x−9,016,823 | 0.9988 |
aThe quantification of these substances was performed on the assumption of the response factor of toluene