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Reaction progress kinetic profiles for the reactions of ArCl 6 with amine 3 plotted as rate vs [ArCl] over the range of concentrations common to the two reactions. The concentration of amine 3 at the point in the reaction progress marked by the dashed line is shown for each reaction. Note a: Pd(L7) is an oxidative addition complex generated in situ from (COD)Pd(CH2TMS)2, L7, and 12 (see the Supporting Information for details).
