Table 1.
Spectroscopic properties of BODIPYs 1a,b, 6a–c, 7a–c, and 8–17 in dichloromethane at room temperature.[a]
BODIPY | Absorption λmax [nm] | log ε [M−1cm−1] | Emission λmax [nm] | Φf | Stokes shift [nm] |
---|---|---|---|---|---|
1a | 517 | 4.80 | 540 | 0.52 | 23 |
1b | 513 | 4.95 | 536 | 0.33 | 23 |
6a | 547 | 4.64 | 591 | 0.097 | 44 |
6b | 586 | 4.78 | 611 | 0.022 | 25 |
6c | 523 | 4.71 | 551 | 0.46 | 28 |
7a | 529 | 4.73 | 548 | 0.09 | 19 |
7b | 535 | 4.78 | 555 | 0.0097 | 20 |
7c | 515 | 4.71 | 536 | 0.48 | 21 |
8 | 577 | 4.53 | 592 | 0.097 | 15 |
9 | 556 | 4.66 | 577 | 0.011 | 21 |
10 | 563 | 4.84 | 582 | 0.022 | 19 |
11 | 505 | 4.52 | 521 | 0.89 | 16 |
12 | 487 | 4.52 | 531 | 0.0017 | 44 |
13 | 582 | 4.35 | 610 | 0.13 | 28 |
14 | 512 | 4.41 | 532 | 0.41 | 20 |
15 | 521 | 4.62 | 570 | 0.94 | 49 |
16 | 587 | 4.22 | 617 | 0.73 | 30 |
17 | 538 | 4.46 | 562 | 0.24 | 24 |
For BODIPYs 1a,b, 6c, 7a, 7c, 11, 12, 14, and 15 the calculation of fluorescence quantum yield used rhodamine 6G in ethanol (0.95) as standard; for BODIPYs 6a, 7b, and 17, rhodamine B in ethanol (0.49) was used as a standard; for BODIPYs 6b, 8–10, 13, and 16, crystal violet perchlorate in methanol (0.54) was used as standard.