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. Author manuscript; available in PMC: 2015 Apr 3.
Published in final edited form as: Angew Chem Int Ed Engl. 2014 Dec 4;54(5):1638–1641. doi: 10.1002/anie.201410326

Scheme 2.

Scheme 2

Previous approaches towards the synthesis of chiral α-aminosilanes and the development of our strategy. Bpin = pinacolborane, Bz = benzoyl, Tol = tolyl.