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Chemical structures of (A) d2-SM and (B) d2-diyne-SM and the NMR spectra of (C) d2-SM/DOPC/chol and (D) d2-diyne-SM/DOPC/chol (molar ratio of 1:1:1) ternary bilayers at 30 °C. The d2-SM/DOPC/chol mixtures gave two Pake doublets at Δν = 51.9 kHz (Lo) and Δν = 36.3 kHz (Ld). The d2-diyne-SM/DOPC/chol mixtures gave a single Pake doublet at Δν = 48.1 kHz (Lo).
