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. Author manuscript; available in PMC: 2015 Apr 20.
Published in final edited form as: Photochem Photobiol. 2014 Jan 16;90(2):313–328. doi: 10.1111/php.12227

Table 3.

Absorption and kinetic properties of N-ethylheterocycle radicals in acetonitrile at room temperature.

Radical Structure* Radical Precursor λmax (nm) kq(O2)§ (M−1 s−1)
graphic file with name nihms596551t15.jpg 6E 510 3.3 × 107
graphic file with name nihms596551t16.jpg 7E 700 7.3 × 108
graphic file with name nihms596551t17.jpg 3E 575 4.3 × 108
*

Several other resonance contributors can be drawn;

Studied as either the tetrafluoroborate or hexafluorophosphate salts;

Approximate absorption maximum of the radical;

§

Rate constant for radical reaction with molecular oxygen.