Table 3.
Absorption and kinetic properties of N-ethylheterocycle radicals in acetonitrile at room temperature.
| Radical Structure* | Radical Precursor† | λmax‡ (nm) | kq•(O2)§ (M−1 s−1) |
|---|---|---|---|
|
6E | 510 | 3.3 × 107 |
|
7E | 700 | 7.3 × 108 |
|
3E | 575 | 4.3 × 108 |
Several other resonance contributors can be drawn;
Studied as either the tetrafluoroborate or hexafluorophosphate salts;
Approximate absorption maximum of the radical;
Rate constant for radical reaction with molecular oxygen.