Table 1.
DEX-HEMA hydrogel swelling ratio measurements and theoretical mesh size calculation
Day | Qm | v2,s | Mc (Da) | ζ (nm) |
---|---|---|---|---|
0 (initial)a) | 6.393 | 0.122b) | - | - |
1 | 5.678 | 0.135 | 1135 | 4.658 |
3 | 6.103 | 0.127 | 1363 | 5.212 |
7 | 6.664 | 0.118 | 1691 | 5.957 |
14 | 8.285 | 0.097 | 2780 | 8.149 |
21 | 9.576 | 0.085 | 3751 | 9.891 |
Molecular weight between crosslinks and mesh size were not calculated for the initial hydrogel (immediately after crosslinking) because the hydrogel had not been submerged in any solution at this time, and thus had not attained swelling equilibrium;
The polymer volume fraction at day 0 is used as V2,r in the modified Flory-Rehner equation.