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The four-step mechanism for the crystallization of homochiral 1D-Mn. The achiral Mn(adc) (2) crystals are formed first in the initial hours and can persist for days in the absence of camphoric acid. However, in the presence of D-camphoric acid, the achiral Mn(adc) is converted into enantioenriched chiral [Mn3(HCOO)4](adc).
