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Z-Olefin synthesis with secondary and tertiary alkyl iodides. The conditions were described in detail in the SI. (a) 4 d. (b) RI (2 equiv), Zn (2 equiv), I2 (3 mol %). (c) RI (3 equiv), Zn (3 equiv), I2 (5 mol %). (d) RI (2.5 equiv), Zn (2.5 equiv), I2 (5 mol %). (e) RI (5 equiv), Zn (5 equiv), I2 (10 mol %). (f) TMEDA (40 mol %) added. (g) FeBr2 (20 mol %), RI (6 equiv), Zn (6 equiv), I2 (10 mol %).
