Table 3. Selected Bond Length Data for {[H(sebenzimMe)]xHg} Compounds.
|
d (Å) |
||
|---|---|---|
| compound | Hg–X | Hg–Se |
| [H(sebenzimMe)]2HgCl2 | 2.4942(7), 2.5727(8) | 2.5732(5), 2.6090(5) |
| [H(sebenzimMe)]3HgCl2 | 2.7506(10), 3.2397(9) | 2.5690(4), 2.5864(4), 2.6730(4) |
| [H(sebenzimMe)]4HgCl2a | – | 2.6203(6), 2.6327(6), 2.7025(6), 27284(7), 2.6260(6), 2.6365(6), 2.6959(6), 2.7267(7) |
| [H(sebenzimMe)]2HgI2 (monoclinic) | 2.7280(3), 2.7463(4) | 2.6850(4), 2.6980(4) |
| [H(sebenzimMe)]2HgI2 (orthorhombic) | 2.7791(7), 2.8041(7) | 2.6149(10), 2.6396(10) |
| [H(sebenzimMe)2HgI | 2.7497(4) | 2.5466(6), 2.5748(6), 3.0904(6), 3.3215(6) |
| [H(sebenzimMe)2]2Hg | – | 2.6230(12), 2.6230(12), 2.6320(12), 2.6367(13) |
a
Values for two crystallographically independent molecules.