| Crystal data |
| Chemical formula |
[Ir2Cl6(CH4O)4]2H2O |
|
M
r
|
380.68 |
| Crystal system, space group |
Triclinic, P
|
| Temperature (K) |
100 |
|
a, b, c () |
7.1445(4), 7.4876(5), 8.6362(7) |
| , , () |
73.597(6), 75.596(5), 89.404(5) |
|
V (3) |
428.37(5) |
|
Z
|
2 |
| Radiation type |
Mo K
|
| (mm1) |
16.46 |
| Crystal size (mm) |
0.14 0.11 0.09 |
| |
| Data collection |
| Diffractometer |
Agilent Xcalibur Eos Gemini ultra |
| Absorption correction |
Gaussian (CrysAlis PRO; Agilent, 2014 ▸) |
|
T
min, T
max
|
0.184, 0.342 |
| No. of measured, independent and observed [I > 2(I)] reflections |
7987, 2817, 2575 |
|
R
int
|
0.040 |
| (sin /)max (1) |
0.750 |
| |
| Refinement |
|
R[F
2 > 2(F
2)], wR(F
2), S
|
0.028, 0.055, 1.03 |
| No. of reflections |
2817 |
| No. of parameters |
93 |
| No. of restraints |
6 |
| H-atom treatment |
H atoms treated by a mixture of independent and constrained refinement |
|
max, min (e 3) |
1.67, 1.94 |
