Table 2. Experimental details.

Crystal data
Chemical formula	[Co(N3)2(C12H8N4S)2]
M r	623.56
Crystal system, space group	Monoclinic, P21/c
Temperature (K)	296
a, b, c ()	7.8004(3), 8.2439(3), 20.3222(8)
()	92.910(2)
V (3)	1305.15(9)
Z	2
Radiation type	Mo K
(mm1)	0.86
Crystal size (mm)	0.39 0.31 0.18
Data collection
Diffractometer	Bruker APEXII CCD
Absorption correction	Multi-scan (SADABS; Bruker, 2009 ▸)
T min, T max	0.640, 0.747
No. of measured, independent and observed [I > 2(I)] reflections	27415, 3667, 2884
R int	0.043
(sin /)max (1)	0.694
Refinement
R[F 2 > 2(F 2)], wR(F 2), S	0.035, 0.088, 1.03
No. of reflections	3667
No. of parameters	187
H-atom treatment	H-atom parameters constrained
max, min (e 3)	0.70, 0.26

Computer programs: APEX2 and SAINT (Bruker, 2009 ▸), SHELXS97 and SHELXL97 (Sheldrick, 2008 ▸), ORTEP-3 for Windows and WinGX (Farrugia, 2012 ▸).