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. Author manuscript; available in PMC: 2015 Aug 19.
Published in final edited form as: Nature. 2015 Jan 21;518(7539):431–434. doi: 10.1038/nature14160

Extended Data Table 1.

Additional vibrational modes of metal centres relevant to Q and T

Vibrational structure System v(Δ18O) cm−1 v16O18O cm−1 Δ2H cm−1 Ref
sMMO Q 690 (−36) 673 0 This work
sMMO T 556 (−23) - 0 This work
graphic file with name nihms-685567-t0009.jpg [FeIV(O)(TMG3tren)] 843 (−33) - - 38
TauD-F4 825 (−37) - 0 12
[FeIV(O)(TMC)(NCCH3)]2+ 834 (−34) - - 39
graphic file with name nihms-685567-t0010.jpg hDOHHperoxo 855a (−44) 833 - 15
Peroxo-Δ9D 898 (−53) 874 - 40
Frog M ferritin peroxo 851 (−51) - - 41
graphic file with name nihms-685567-t0011.jpg hDOHHperoxo 473 (−16) 465 - 15
Peroxo-Δ9D 442 (−17) 433 - 40
Frog M ferritin peroxo 485 (−17) 477 - 41
a

represents the center of a Fermi Doublet

References 38-41 are cited in this Table.