Table 4. Experimental details.

Crystal data
Chemical formula	[Co(C22H26N4O4)]PF6
M r	614.37
Crystal system, space group	Orthorhombic, I b c a
Temperature (K)	100
a, b, c ()	13.9848(4), 14.6221(4), 22.2177(6)
V (3)	4543.2(2)
Z	8
Radiation type	Mo K
(mm1)	0.92
Crystal size (mm)	0.44 0.36 0.21
Data collection
Diffractometer	Bruker APEXII equipped with a CCD detector
Absorption correction	Multi-scan (SADABS; Bruker, 2008 ▸)
T min, T max	0.691, 0.834
No. of measured, independent and observed [I > 2(I)] reflections	57644, 3630, 3401
R int	0.017
(sin /)max (1)	0.725
Refinement
R[F 2 > 2(F 2)], wR(F 2), S	0.027, 0.079, 1.12
No. of reflections	3630
No. of parameters	174
H-atom treatment	H-atom parameters constrained
max, min (e 3)	0.66, 0.52

Computer programs: APEX2 and SAINT (Bruker, 2008 ▸), SHELXS97 (Sheldrick, 2008 ▸), SHELXL2014 (Sheldrick, 2015 ▸), ORTEP-3 for Windows (Farrugia, 2012 ▸), enCIFer (Allen et al., 2004 ▸) and publCIF (Westrip, 2010 ▸).