Symbol Equation | ||
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a | Radius of DNA in cylindrical model | |
b | Axial charge separation in cylindrical model of DNA | |
R | Gas constant, 1.9859 (cal K−1 mol−1) | |
T | Temperature | |
∣ZD∣ | Number of phosphate charges in DNA oligomer | |
Gcoul | Coulombic Gibbs free energy | |
Gcoul/∣ZD∣ | Coulombic Gibbs free energy per phosphate charge |
|
Polymeric limit of Coulombic Gibbs free energy |
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ncoul | −(RT)−1∂Gcoul/∂ln C | Salt ion association |
Tm | Transition temperature | |
STm | dTm/dln C | Salt-dependence of transition temperature |
Kobs | Observed equilibrium constant | |
−RTln Kobs | Standard free energy change | |
SKobs | ∂ln Kobs/∂ln C | Salt-dependence of equilibrium constant |
Coefficients of DNA oligomeric model at C = 0.15 M | ||
Ne | Characteristic length of CEE | |
Gu,0 | Per phosphate free energy of oligomer at ∣ZD∣ = 0 |
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First ∣ZD∣-derivative of per phosphate oligomer free energy at ∣ZD∣ = 0 |
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Gu,∞ | Per phosphate free energy of polymer | |
2g | Negative first derivative of per phosphate free energy with respect to 1/∣ZD∣ at ∣ZD∣ → ∞ |
|
nu,0 | Per phosphate salt ion association of oligomer at ∣ZD∣ = 0 |
|
First ∣ZD∣-derivative of per phosphate salt ion association at ∣ZD∣ = 0 |
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nu,∞ | Per phosphate salt ion association of polymer |
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2γ | Negative first derivative of per phosphate salt ion association with respect to 1/∣ZD∣ at ∣ZD∣ → ∞ |