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. Author manuscript; available in PMC: 2015 May 21.
Published in final edited form as: ChemMedChem. 2014 May 6;9(8):1892–1901. doi: 10.1002/cmdc.201402033

Table 1.

Summary of initial rates for ascorbic acid consumption promoted by CuII–ATCUN complexes.

Complex Source protein Initial rate [μm min−1]a
with H2O2 without H2O2
Cu–DAH Human serum albumin   1.45 ± 0.07   0.20 ± 0.02
Cu–DMH Neuromedin K   1.36 ± 0.02   0.16 ± 0.01
Cu–DSH Histatin 5   1.31 ± 0.03   0.13 ± 0.01
Cu–DTH Bovine serum albumin   2.89 ± 0.07   1.28 ± 0.06
Cu–EAH Rat serum albumin   1.14 ± 0.04   0.12 ± 0.02
Cu–GGH Simplest ATCUN 52.54 ± 0.76 19.35 ± 0.43
Cu–GKH –   1.21 ± 0.09   0.13 ± 0.01
Cu–GNH Neuromedin C   1.15 ± 0.04   0.096 ± 0.002
Cu–LKH Xnf7 10.8 ± 0.27   4.52 ± 0.17
Cu–NGH Met Lyase   1.29 ± 0.09   0.18 ± 0.01
Cu–RTH Human protamine 2 13.12 ± 0.27   5.67 ± 0.20
Cu–SMH Human TBX3   1.39 ± 0.04   0.11 ± 0.01
Cu–VIH – 39.21 ± 1.08 15.5 ± 0.07
Cu2+ only – 57.21 ± 0.81 20.03 ± 0.37
No Cu–XXH –   1.13 ± 0.03   0.19 ± 0.02
a

Data represent the mean ± standard deviation of three independent experiments.