Table 1. 1H NMR (500 MHz) and 13C NMR (125 MHz) spectral data of polycerasoidin in CDCl3 (δ in ppm, J in Hz).
Position | 1H-NMR (δ ppm) | 13C-NMR (δ ppm) |
---|---|---|
1 | 2.71 m 2.58 m | 22.6 |
2 | 1.74 m | 31.4 |
3 | - | 76.7 |
4 | 1.62 m | 39.6 |
5 | 2.14 m | 22.1 |
6 | 5.14 t (6.9) | 125.1 |
7 | - | 134.2 |
8 | 2.05 m | 39.0 |
9 | 2.12 m | 28.1 |
10 | 6.02 t (6.9) | 146.1 |
11 | - | 127.2 |
12 | 2.12 s | 20.4 |
13 | - | 172.3 |
14 | 1.62 s | 16.2 |
15 | 1.25 s | 24.0 |
16 | 1.89 s | 16.2 |
1` | - | 120.8 |
2` | - | 120.8 |
3` | 6.43 d (2.12) | 114.7 |
4` | - | 152.1 |
5` | 6.55 d (2.12) | 111.0 |
6` | - | 126.0 |
OMe | 3.72 s | 55.6 |