Table 1. Electrical Properties of M2(DEBDC) (M = Fe, Mn; E = S, O).
| Fe2(DSBDC) | Mn2(DSBDC) | Fe2(DOBDC) | Mn2(DOBDC) | |
|---|---|---|---|---|
| σas-synthesized (S/cm)a | 3.9 × 10–6 | 2.5 × 10–12 | 3.2 × 10–7 | 3.9 × 10–13 |
| σguest-free (S/cm)b | 5.8 × 10–7 | 1.2 × 10–12 | 4.8 × 10–8 | 3.0 × 10–13 |
| Ea (eV)c | 0.27 | 0.81 | 0.41 | 0.55 |
| Eg (eV)d | 1.92 | 2.60 | 1.47 | 2.48 |
| Φ (eV)e | 3.71 | 3.81 | 2.81 | 3.72 |
a
Electrical conductivity of M2(DEBDC)(DMF)2·x(DMF) at 297 K.
b
Electrical conductivity of M2(DEBDC)(DMF)2 at 297 K.
c
Activation energy of M2(DEBDC)(DMF)2.
d
Calculated bandgap of M2(DEBDC)(DMF)2.
e
Calculated work function of M2(DEBDC)(DMF)2.