Figure 1.
Naturally occurring and synthetically useful compounds bearing terminal methoxyvinyl groups. a - E-methoxyvinylglycine (natural; PLP enzyme inhibitor); b Z-methoxyvinylglycine (synthetic; SAM synthetase inhibitor); c isoquinolone anti-tumor agent; d fungal antibiotic eupenicinical B; e megistoquinone II antibiotic (natural); f asymmetric methoxyallylating agent (synthetic); g inverse electron demand dienophile (synthetic)
