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. 2015 May 11;112(21):6551–6555. doi: 10.1073/pnas.1507441112

Table 1.

Measured enthalpies of drop solution and enthalpies of formation from oxides

Source ΔHds, kJ/mol ΔHf,ox, kJ/mol
Coffinite-F −121.43 ± 1.54* 24.6 ± 3.1
−102.01 ± 3.10 26.7 ± 4.7
Coffinite-G 44.14 ± 0.94* (−5.5 ± 3.5)
44.14 ± 0.94* 24.1 ± 3.5
44.39 ± 0.94* 23.9 ± 4.0§
*

Measured in 3Na2O·4MoO3 solvent.

Measured in 2PbO·B2O3 solvent.

This value obtained from a correction considering the water was strongly bonded and its interaction enthalpy was assumed to be −80 kJ/mol.

§

This value obtained from a correction considering metaschoepite as an impurity phase containing all of the water.