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. 2015 May 12;54(21):3231–3234. doi: 10.1021/acs.biochem.5b00416

Scheme 1. Proposed CarH Photolysis Mechanism.

Scheme 1

See the text for details. C4′ and C5′ of the 5′-deoxyadenosyl group are labeled. Cobalamin is shown as a rhombus with the Co oxidation state indicated. The lower axial nitrogen ligand is denoted as N. The adenine base is abbreviated as Ad.