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. Author manuscript; available in PMC: 2015 Jun 9.
Published in final edited form as: Dalton Trans. 2011 Aug 18;40(37):9557–9565. doi: 10.1039/c1dt10995b

Table 4.

Redox potential of ferrocenoyl esters in CH3CN 0.1 M [NBun4]PF6 at a scan rate of 100 mV s−1, using Ag/AgCl saturated as standard electrode. The Ferrocenoyl concentration was 2 × 10−3 M

Complex: Ferrocenoyl − Epa(mV) Epc(mV) ΔE(mV) E1/2(mV)
17b-hydroxy-estra-1,3,5(10)-trien-3-olate 801 711 90 756
3β-estra1,3,5(10)-trien-17-one-3-olate 827 735 92 781
(3β,5Z,7E,22E)-9,10-secoergosta5,7,10(19),22-tetraen-3-olate 770 656 90 713
Fc/Fc+ 494 414 84 452