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. Author manuscript; available in PMC: 2016 May 27.
Published in final edited form as: J Am Chem Soc. 2015 May 14;137(20):6602–6615. doi: 10.1021/jacs.5b02174

Figure 4.

Figure 4

UV–vis spectra of (a) [(F8)FeIII−O−CuII(tmpa)]-[B(C6F5)4] (red), (F8)FeII(NO) (blue) generated from addition of 1 mL of NO(g) to the solution 75 µM in acetone in a 2 mm cuvette at −40 °C, after 30 min and (b) [(F8)FeIII−O−CuII(MePY2)]-[B(C6F5)4] (red) and (F8)FeII(NO) (blue) promptly generated after addition of 1 mL NO(g) into the µ-oxo complex solution 50 µM in acetone in a 2 mm cuvette at −40 °C.