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HPLC–MS analysis of the products of Ela-TE action on model substrates. A) Compounds 4 and 5, as well as the hydrolysis product 3 a, are generated from 3 b by Ela-TE. DEBS-TE exclusively catalyzes hydrolysis to 3 a. B) Compound 4, when purified from the reaction mixture and re-incubated with fresh Ela-TE, is cyclized into 5.
