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Photocatalytic CO production from CO2 under λ>420 nm irradiation with the ReP–TiO2 hybrid system compared to homogeneous [ReCl(bpy)(CO)3] with and without TiO2 and RePBr in solution (RePpic is insoluble in DMF). 0.1 μmol Re catalyst in 4.5 mL DMF/TEOA 5:1 was used with 5 mg TiO2. TONCO=molCO molRe−1.
