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. 2015 Apr 21;26(7):1191–1203. doi: 10.1007/s13361-015-1122-1

Scheme 4.

Scheme 4

Reaction of 2-nitrothiophene 5-anion with chloroacetonitrile and methyl chloroacetate according to proton transfer followed by σH-adduct formation and elimination of HCl