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. Author manuscript; available in PMC: 2016 Jun 15.
Published in final edited form as: Inorg Chem. 2015 May 22;54(12):5717–5724. doi: 10.1021/acs.inorgchem.5b00290

Figure 4.

Figure 4

ORTEP of Ni[(SCH2)2NBn](dcpe)·CH2Cl2, showing one of the crystallographically independent complexes with ellipsoids drawn at the 50% probability level. H atoms, solvate, and disorder are omitted for clarity. Selected distances (Å): Ni1−S1, 2.1952(19); Ni1−S2, 2.1841(18); Ni1−P1, 2.1884(18); Ni1−P2, 2.1866(18); Ni2−S3, 2.1860(19); Ni2−S4, 2.176(2); Ni2−P3, 2.1774(19); Ni2−P4, 2.1797(18). Selected angles (deg): S1−Ni1−S2, 100.01(7); P1−Ni1−P2, 88.07(7); P1−Ni1−S1, 85.69(7); P2−Ni1−S1, 173.39(7); P1−Ni1−S2, 173.94(8); P2−Ni1−S2, 86.31(7); C27−N1−C28, 113.5(6), C27−N1−C29, 111.3(6); C28−N1−C29, 115.0(6). S4−Ni2−S3, 100.01(8); P3−Ni2−P4, 88.77(7); P3−Ni2−S3, 85.97(7); P4−Ni2−S3, 170.30(8); S4−Ni2−P3, 170.71(9); S4−Ni2−P4, 86.28(7); C62−N2−C63, 112.5(6); C62−N2−C64, 114.7(6); C63−N2−C64, 114.5(6).