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. 2014 Aug 21;82(4):835–846. doi: 10.3797/scipharm.1404-02

Tab. 1.

1H- and 13C-NMR data of the new hydroxycinnamoyl aldonic acid derivatives 9 and 11 (in CD3OD = δ 3.30 ppm: M = multiplicity)

  9 11 9 11
H/C (ppm) J(Hz) M (ppm) J(Hz) M (ppm) (ppm)
1             172.2 175.8
2 5.28 2.4 d 4.25 2.0 d 73.6 72.3
3 4.20 2.4, 5.0, 9.0 ddd 4.22 2.0, 6.0, 8.0 ddd 72.7 72.2
4a 3.63 6.0, -11.0 dd 4.27 8.0, -11.0 dd 63.1 65.9
4b 3.61 8.0, -11.0 dd 4.26 6.0, -11.0 dd    
1’             127.8 127.2
2’ 7.08 2.1 d 7.46 8.5, 2.3 dd 115.3 131.2
3’       6.80 8.5, 2.3 dd 146.8 116.8
4’             149.7 161.2
5’ 6.79 8.2 d 6.80 8.5, 2.3 dd 116.5 116.8
6’ 6.79 2.1, 8.2 dd 7.46 8.5, 2.3 dd 123.1 131.2
7’ 7.68 15.8 d 7.64 16.0 d 147.9 146.8
8’ 6.37 15.8 d 6.35 16.0 d 114.4 115.0
9’             168.5 169.0