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. Author manuscript; available in PMC: 2016 Mar 12.
Published in final edited form as: J Phys Chem B. 2015 Feb 26;119(10):4155–4164. doi: 10.1021/acs.jpcb.5b00808

Table 3.

Absolute Number of Bonds or Functional Groups on the Fabricated Surfaces per Grama

solid
support
Si−OH C−OH C−H C−F sens C−OH:
C−F:sens
Si−OH:
C−F:sens
fluorinated
silica 7
1.3×1020 - 3.5×1021 7.8×1021 5.5×1016 - 2400:142000:1
Teflon/PVA 10 - 6.2×1020 1.9×1021 9.6×1021 1.3×1016 48000:750000:1 -
a

Fluorinated silica 7 contains pendent nonafluorosilane groups. Teflon/PVA 10 contains repeating –[CF2-CF2]m– and –[CH2-CH(OH)]n– units. The penetration depth of sensitizer into solid 7 was 0.08 mm and into solid 10 was 1.0 mm.